Issue 31, 2014
From the journal:

Chemical Communications

Manganese-catalyzed intermolecular C–H/C–H coupling of carbonyls and heteroarenes†

Keika Hattori,a   Asraa Ziadi,a   Kenichiro Itamiab  and  Junichiro Yamaguchi*a  

* Corresponding authors

a Institute of Transformative Bio-Molecules (WPI-ITbM) and Department of Chemistry, Graduate School of Science, Nagoya University, Chikusa, Nagoya 464-8602, Japan
E-mail: junichiro@chem.nagoya-u.ac.jp

b JST, ERATO, Itami Molecular Nanocarbon Project, Nagoya University, Chikusa, Nagoya 464-8602, Japan

Abstract

Manganese-catalyzed intermolecular C–H/C–H coupling of carbonyls and heteroarenes has been developed. The presence of NaIO4 as an oxidant is crucial for the catalytic reaction. These new, inexpensive reaction conditions allow the gram-scale synthesis of α-heteroaryl carboxylic acids.

Graphical abstract: Manganese-catalyzed intermolecular C–H/C–H coupling of carbonyls and heteroarenes

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Article information

DOI
https://doi.org/10.1039/C4CC01376J
Article type
Communication
Submitted
24 Jan 2014
Accepted
04 Mar 2014
First published
04 Mar 2014

Chem. Commun., 2014,50, 4105-4107

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Manganese-catalyzed intermolecular C–H/C–H coupling of carbonyls and heteroarenes

K. Hattori, A. Ziadi, K. Itami and J. Yamaguchi, Chem. Commun., 2014, 50, 4105 DOI: 10.1039/C4CC01376J

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