Issue 22, 2014
From the journal:

Chemical Communications

A second-generation ligand for the enantioselective rhodium-catalyzed addition of arylboronic acids to alkenylazaarenes†

Iain D. Roy,a   Alan R. Burns,ab   Graham Pattison,a   Boris Michel,a   Alexandra J. Parkerc  and  Hon Wai Lam*ab  

* Corresponding authors

a EaStCHEM, School of Chemistry, University of Edinburgh, Joseph Black Building, The King's Buildings, West Mains Road, Edinburgh, UK

b School of Chemistry, University of Nottingham, University Park, Nottingham, UK
E-mail: hon.lam@nottingham.ac.uk
Tel: +44 (0)115-748-4677

c AstraZeneca Process Research and Development, Charter Way, Silk Road Business Park, Macclesfield, Cheshire, UK

Abstract

A 2,4,6-trialkylanilide-containing chiral diene has been identified as a superior ligand for the enantioselective rhodium-catalyzed arylation of alkenylazaarenes with arylboronic acids.

Graphical abstract: A second-generation ligand for the enantioselective rhodium-catalyzed addition of arylboronic acids to alkenylazaarenes

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Article information

DOI
https://doi.org/10.1039/C4CC00340C
Article type
Communication
Submitted
15 Jan 2014
Accepted
24 Jan 2014
First published
03 Feb 2014

Chem. Commun., 2014,50, 2865-2868

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A second-generation ligand for the enantioselective rhodium-catalyzed addition of arylboronic acids to alkenylazaarenes

I. D. Roy, A. R. Burns, G. Pattison, B. Michel, A. J. Parker and H. W. Lam, Chem. Commun., 2014, 50, 2865 DOI: 10.1039/C4CC00340C

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