Issue 15, 2014

Versatile ruthenium(ii)-catalyzed C–H cyanations of benzamides

Abstract

Direct cyanations of arenes and heteroarenes bearing only weakly coordinating amides were accomplished using a robust ruthenium(II) catalyst. The user-friendly C(sp2)–H activation occurred with the assistance of carboxylate with high site-selectivity, excellent functional group tolerance and ample scope.

Graphical abstract: Versatile ruthenium(ii)-catalyzed C–H cyanations of benzamides

Supplementary files

Article information

Article type
Communication
Submitted
15 Dec 2013
Accepted
02 Jan 2014
First published
06 Jan 2014
This article is Open Access
Creative Commons BY license

Chem. Commun., 2014,50, 1878-1881

Versatile ruthenium(II)-catalyzed C–H cyanations of benzamides

W. Liu and L. Ackermann, Chem. Commun., 2014, 50, 1878 DOI: 10.1039/C3CC49502G

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