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Issue 75, 2014
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Iridium complexes of new NCP pincer ligands: catalytic alkane dehydrogenation and alkene isomerization

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Abstract

Iridium complexes of novel NCP pincer ligands containing pyridine and phosphinite arms have been synthesized. One Ir complex shows good catalytic activity for alkane dehydrogenation, and all complexes are highly active for olefin isomerization. A combination of the Ir complex and a (PNN)Fe pincer complex catalyzes the formation of linear alkylboronates selectively from internal olefins via sequential olefin isomerization–hydroboration.

Graphical abstract: Iridium complexes of new NCP pincer ligands: catalytic alkane dehydrogenation and alkene isomerization

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Submitted
07 Sep 2013
Accepted
29 Jul 2014
First published
29 Jul 2014

Chem. Commun., 2014,50, 11056-11059
Article type
Communication

Iridium complexes of new NCP pincer ligands: catalytic alkane dehydrogenation and alkene isomerization

X. Jia, L. Zhang, C. Qin, X. Leng and Z. Huang, Chem. Commun., 2014, 50, 11056
DOI: 10.1039/C3CC46851H

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