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Issue 75, 2014
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Cu-Catalyzed Suzuki–Miyaura reactions of primary and secondary benzyl halides with arylboronates

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Abstract

A copper-catalyzed Suzuki–Miyaura coupling of benzyl halides with arylboronates is described. Varieties of primary benzyl halides as well as more challenging secondary benzyl halides with β hydrogens or steric hindrance could be successfully converted into the corresponding products. Thus it provides access to diarylmethanes, diarylethanes and triarylmethanes.

Graphical abstract: Cu-Catalyzed Suzuki–Miyaura reactions of primary and secondary benzyl halides with arylboronates

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Publication details

The article was received on 12 Jul 2014, accepted on 29 Jul 2014 and first published on 31 Jul 2014


Article type: Communication
DOI: 10.1039/C4CC05376A
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Citation: Chem. Commun., 2014,50, 11060-11062
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    Cu-Catalyzed Suzuki–Miyaura reactions of primary and secondary benzyl halides with arylboronates

    Y. Sun, J. Yi, X. Lu, Z. Zhang, B. Xiao and Y. Fu, Chem. Commun., 2014, 50, 11060
    DOI: 10.1039/C4CC05376A

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