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Issue 45, 2014
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Ester-substituted cyclometallated rhodium and iridium coordination assemblies with π-bonded dioxolene ligand: synthesis, structures and luminescent properties

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Abstract

A series of functionalized cyclometallated rhodium and iridium coordination assemblies 2–7 displaying a π-bonded dioxolene ligand is described. The X-ray molecular structures of two of the above compounds showed the formation of a 1D supramolecular chain mediated by π–π interactions among individual units. The luminescent properties of these compounds are presented and discussed. These results show that the stacking interactions are retained also in solution and emission from excited dimeric species is observed.

Graphical abstract: Ester-substituted cyclometallated rhodium and iridium coordination assemblies with π-bonded dioxolene ligand: synthesis, structures and luminescent properties

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Publication details

The article was received on 10 Feb 2014, accepted on 14 May 2014 and first published on 05 Jun 2014


Article type: Paper
DOI: 10.1039/C4RA01185F
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RSC Adv., 2014,4, 23740-23748

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    Ester-substituted cyclometallated rhodium and iridium coordination assemblies with π-bonded dioxolene ligand: synthesis, structures and luminescent properties

    A. Damas, H. Sesolis, M. N. Rager, L. M. Chamoreau, M. P. Gullo, A. Barbieri and H. Amouri, RSC Adv., 2014, 4, 23740
    DOI: 10.1039/C4RA01185F

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