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Issue 7, 2014
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Magnetically recyclable magnetite–palladium (Nanocat-Fe–Pd) nanocatalyst for the Buchwald–Hartwig reaction

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Abstract

The immobilization of Pd on the magnetite surface afforded Nanocat-Fe–Pd using inexpensive precursors and its catalytic role in the Buchwald–Hartwig reaction for arylation of amines and amides was investigated; C–N bond formation was achieved in moderate to excellent yields and the catalyst could be separated and recycled up to five cycles by magnetic decantation without a significant loss in yield.

Graphical abstract: Magnetically recyclable magnetite–palladium (Nanocat-Fe–Pd) nanocatalyst for the Buchwald–Hartwig reaction

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Article information


Submitted
30 Mar 2014
Accepted
17 Apr 2014
First published
22 Apr 2014

Green Chem., 2014,16, 3494-3500
Article type
Paper
Author version available

Magnetically recyclable magnetite–palladium (Nanocat-Fe–Pd) nanocatalyst for the Buchwald–Hartwig reaction

S. Sá, M. B. Gawande, A. Velhinho, J. P. Veiga, N. Bundaleski, J. Trigueiro, A. Tolstogouzov, O. M. N. D. Teodoro, R. Zboril, R. S. Varma and P. S. Branco, Green Chem., 2014, 16, 3494
DOI: 10.1039/C4GC00558A

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