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Issue 23, 2014
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Pincer versus pseudopincer: isomerism in palladium(ii) complexes bearing κ3C,S,C ligands

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Abstract

In NHC pincer complexes incorporating a hemilabile donor site, there exists an equilibrium between the true pincer form and a pseudopincer coordination isomer. The influence of the NHC moieties on this isomerism has been studied by DFT calculations.

Graphical abstract: Pincer versus pseudopincer: isomerism in palladium(ii) complexes bearing κ3C,S,C ligands

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Article information


Submitted
09 Apr 2014
Accepted
14 Apr 2014
First published
14 Apr 2014

This article is Open Access

Dalton Trans., 2014,43, 8591-8594
Article type
Communication
Author version available

Pincer versus pseudopincer: isomerism in palladium(II) complexes bearing κ3C,S,C ligands

J. C. Bernhammer, G. Frison and H. V. Huynh, Dalton Trans., 2014, 43, 8591
DOI: 10.1039/C4DT01047G

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