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Issue 12, 2014
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A copper complex supported by an N2S-tridentate ligand inducing efficient heterolytic O–O bond cleavage of alkylhydroperoxide

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Abstract

We have recently reported a copper(II)-superoxide complex supported by an N3-tridentate ligand (LN3), which exhibits a similar structure and reactivity to those of a putative reactive intermediate involved in the catalytic reactions of copper monooxygenases such as peptidylglycine α-hydroxylating monooxygenase (PHM) and dopamine β-monooxygenase (DβM). In this study, we have synthesised and characterised copper complexes supported by a related sulphur-containing ligand (LN2S) to get insight into the notable electronic effect of the sulphur donor atom in the reaction with cumene hydroperoxide, inducing efficient heterolytic O–O bond cleavage.

Graphical abstract: A copper complex supported by an N2S-tridentate ligand inducing efficient heterolytic O–O bond cleavage of alkylhydroperoxide

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Publication details

The article was received on 19 Oct 2013, accepted on 09 Jan 2014 and first published on 13 Jan 2014


Article type: Paper
DOI: 10.1039/C3DT52952E
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Dalton Trans., 2014,43, 4871-4877
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    A copper complex supported by an N2S-tridentate ligand inducing efficient heterolytic O–O bond cleavage of alkylhydroperoxide

    T. Tano, K. Mieda, H. Sugimoto, T. Ogura and S. Itoh, Dalton Trans., 2014, 43, 4871
    DOI: 10.1039/C3DT52952E

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