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Issue 24, 2014
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Improved efficiency of bulk heterojunction hybrid solar cells by utilizing CdSe quantum dot–graphene nanocomposites

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Abstract

We present a significant efficiency enhancement of hybrid bulk heterojunction solar cells by utilizing CdSe quantum dots attached to reduced graphene oxide (rGO) as the electron accepting phase, blended with the PCPDTBT polymer. The quantum dot attachment to rGO was achieved following a self-assembly approach, recently developed, using thiolated reduced graphene oxide (TrGO) to form a TrGO–CdSe nanocomposite. Therefore, we are able to obtain TrGO–CdSe quantum dot/PCPDTBT bulk-heterojunction hybrid solar cells with power conversion efficiencies of up to 4.2%, compared with up to 3% for CdSe quantum dot/PCPDTBT devices. The improvement is mainly due to an increase of the open-circuit voltage from 0.55 V to 0.72 V. We found evidence for a significant change in the heterojunction donor–acceptor blend nanomorphology, observable by a more vertical alignment of the TrGO-quantum dot nanocomposites in the z-direction and a different nanophase separation in the xy direction compared to the quantum dot only containing device. Moreover, an improved charge extraction and trap state reduction were observed for TrGO containing hybrid solar cells.

Graphical abstract: Improved efficiency of bulk heterojunction hybrid solar cells by utilizing CdSe quantum dot–graphene nanocomposites

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Supplementary files

Article information


Submitted
10 Apr 2014
Accepted
24 Apr 2014
First published
24 Apr 2014

This article is Open Access

Phys. Chem. Chem. Phys., 2014,16, 12251-12260
Article type
Paper
Author version available

Improved efficiency of bulk heterojunction hybrid solar cells by utilizing CdSe quantum dot–graphene nanocomposites

M. Eck, C. V. Pham, S. Züfle, M. Neukom, M. Sessler, D. Scheunemann, E. Erdem, S. Weber, H. Borchert, B. Ruhstaller and M. Krüger, Phys. Chem. Chem. Phys., 2014, 16, 12251
DOI: 10.1039/C4CP01566E

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