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Issue 37, 2014
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Two porous metal–organic frameworks containing zinc–calcium clusters and calcium cluster chains

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Abstract

A two-dimensional metal–organic framework (MOF) containing both Zn(II) and Ca(II) centres and a three-dimensional MOF containing only Ca(II) centres have the largest surface areas (BET 1560 and 914 m2 g−1, respectively) among the reported Ca-based MOFs and also exhibit high gas uptake up to 1 bar for H2 at 77 K and CO2 at 298 K.

Graphical abstract: Two porous metal–organic frameworks containing zinc–calcium clusters and calcium cluster chains

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Supplementary files

Article information


Submitted
17 Jun 2014
Accepted
28 Jul 2014
First published
29 Jul 2014

CrystEngComm, 2014,16, 8664-8668
Article type
Communication
Author version available

Two porous metal–organic frameworks containing zinc–calcium clusters and calcium cluster chains

K. Noh, N. Ko, H. J. Park, S. Park and J. Kim, CrystEngComm, 2014, 16, 8664
DOI: 10.1039/C4CE01237B

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