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Issue 37, 2014
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Influence of an amine group on the highly efficient reversible adsorption of iodine in two novel isoreticular interpenetrated pillared-layer microporous metal–organic frameworks

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Abstract

Two isoreticular microporous Zn(II)-MOFs were constructed using a bipyridyl-type linker mixed into two homologous ligands, 1,4-benzenedicarboxylate, [Zn2(BDC)2(4-bpdh)]·3DMF (TMU-16) and amino-1,4-benzenedicarboxylate, [Zn2(NH2-BDC)2(4-bpdh)]·3DMF (TMU-16-NH2). Both unmodified and amino functionalized MOFs can serve as a host for encapsulating I2. In particular, the amino functionalized MOF can find more applications for the encapsulation of iodine.

Graphical abstract: Influence of an amine group on the highly efficient reversible adsorption of iodine in two novel isoreticular interpenetrated pillared-layer microporous metal–organic frameworks

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The article was received on 30 Jun 2014, accepted on 27 Jul 2014 and first published on 28 Jul 2014


Article type: Communication
DOI: 10.1039/C4CE01331J
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Citation: CrystEngComm, 2014,16, 8660-8663
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    Influence of an amine group on the highly efficient reversible adsorption of iodine in two novel isoreticular interpenetrated pillared-layer microporous metal–organic frameworks

    V. Safarifard and A. Morsali, CrystEngComm, 2014, 16, 8660
    DOI: 10.1039/C4CE01331J

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