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Issue 94, 2014
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The first route to highly stable crystalline microporous zirconium phosphonate metal–organic frameworks

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Abstract

The first crystalline microporous zirconium phosphonate metal–organic framework (UPG-1) was synthesized using the novel tritopic ligand 2,4,6-tris(4-(phosphonomethyl)phenyl)-1,3,5-triazine. Its crystal structure was solved ab initio from laboratory powder X-ray diffraction data. UPG-1 displays remarkable thermal stability and hydrolysis resistance and has a good absorption affinity towards n-butane and CO2.

Graphical abstract: The first route to highly stable crystalline microporous zirconium phosphonate metal–organic frameworks

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Submitted
08 Aug 2014
Accepted
08 Oct 2014
First published
08 Oct 2014

Chem. Commun., 2014,50, 14831-14834
Article type
Communication
Author version available

The first route to highly stable crystalline microporous zirconium phosphonate metal–organic frameworks

M. Taddei, F. Costantino, F. Marmottini, A. Comotti, P. Sozzani and R. Vivani, Chem. Commun., 2014, 50, 14831
DOI: 10.1039/C4CC06223J

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