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Issue 83, 2014
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Fluorinative hydrolysis of phosphorothioic acid esters with a binaphthyl group through axis-to-center chirality transfer leading to the formation of P-chiral phosphorothioic monofluoridic acid salts

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Abstract

Asymmetric synthesis of P-chiral phosphorothioic monofluoridic acid ammonium salts was achieved via axis-to-center chirality transfer reactions by using phosphorothioic acid O-esters with a binaphthyl group, and the absolute stereochemistry of the salts was determined by X-ray analyses and by comparison of their CD spectra.

Graphical abstract: Fluorinative hydrolysis of phosphorothioic acid esters with a binaphthyl group through axis-to-center chirality transfer leading to the formation of P-chiral phosphorothioic monofluoridic acid salts

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Publication details

The article was received on 07 Jul 2014, accepted on 28 Aug 2014 and first published on 28 Aug 2014


Article type: Communication
DOI: 10.1039/C4CC05198J
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Chem. Commun., 2014,50, 12473-12475

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    Fluorinative hydrolysis of phosphorothioic acid esters with a binaphthyl group through axis-to-center chirality transfer leading to the formation of P-chiral phosphorothioic monofluoridic acid salts

    T. Murai, T. Hayashi, K. Yamada, Y. Maekawa and M. Minoura, Chem. Commun., 2014, 50, 12473
    DOI: 10.1039/C4CC05198J

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