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Issue 86, 2014
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The crucial roles of MgCl2 as a non-innocent additive in the Ni-catalyzed carboxylation of benzyl halide with CO2

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Abstract

Ni-catalyzed carboxylation of the C(sp3)–Cl bond with CO2 in the presence of MgCl2 was theoretically investigated. MgCl2 plays three crucial roles in stabilization of a NiI–CO2 adduct and acceleration of the CO2 insertion as a non-innocent additive and the one-electron reduction process as one kind of reagent.

Graphical abstract: The crucial roles of MgCl2 as a non-innocent additive in the Ni-catalyzed carboxylation of benzyl halide with CO2

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The article was received on 29 Jun 2014, accepted on 03 Sep 2014 and first published on 03 Sep 2014


Article type: Communication
DOI: 10.1039/C4CC04962D
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Chem. Commun., 2014,50, 13026-13029

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    The crucial roles of MgCl2 as a non-innocent additive in the Ni-catalyzed carboxylation of benzyl halide with CO2

    F. B. Sayyed and S. Sakaki, Chem. Commun., 2014, 50, 13026
    DOI: 10.1039/C4CC04962D

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