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Issue 96, 2014
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When gold meets chiral Brønsted acid catalysts: extending the boundaries of enantioselective gold catalysis

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Abstract

This review describes the development in the use of Au(I)/Brønsted acid binary catalytic systems to enable an enantioselective transformation in one-pot that cannot be achieved by gold catalysts alone. The examples discussed herein are promising since apart from using chiral ligands there exists a possibility of using chiral Brønsted acids. Clearly, the horizon for enantioselective gold catalysis has been expanded as more options to make the gold-catalyzed reactions enantioselective have become available.

Graphical abstract: When gold meets chiral Brønsted acid catalysts: extending the boundaries of enantioselective gold catalysis

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Publication details

The article was received on 18 Jun 2014, accepted on 14 Aug 2014 and first published on 14 Aug 2014


Article type: Feature Article
DOI: 10.1039/C4CC04633A
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Chem. Commun., 2014,50, 15124-15135

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    When gold meets chiral Brønsted acid catalysts: extending the boundaries of enantioselective gold catalysis

    S. M. Inamdar, A. Konala and N. T. Patil, Chem. Commun., 2014, 50, 15124
    DOI: 10.1039/C4CC04633A

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