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Issue 71, 2014
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Order-to-disorder structural transformation of a coordination polymer and its influence on proton conduction

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Abstract

We observed an ordered-to-disordered structural transformation in a Cu2+ coordination polymer and investigated its influence on the proton conductivity. The transformation generated highly mobile proton carriers in the structure. The resulting material exhibited a conductivity greater than 10−2 S cm−1 at 130 °C. The structural transformation and the conduction mechanism were investigated by EXAFS, TPD-MS and NMR.

Graphical abstract: Order-to-disorder structural transformation of a coordination polymer and its influence on proton conduction

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Supplementary files

Article information


Submitted
09 Jun 2014
Accepted
14 Jul 2014
First published
16 Jul 2014

Chem. Commun., 2014,50, 10241-10243
Article type
Communication
Author version available

Order-to-disorder structural transformation of a coordination polymer and its influence on proton conduction

S. Horike, W. Chen, T. Itakura, M. Inukai, D. Umeyama, H. Asakura and S. Kitagawa, Chem. Commun., 2014, 50, 10241
DOI: 10.1039/C4CC04370G

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