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Issue 31, 2014
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Manganese-catalyzed intermolecular C–H/C–H coupling of carbonyls and heteroarenes

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Abstract

Manganese-catalyzed intermolecular C–H/C–H coupling of carbonyls and heteroarenes has been developed. The presence of NaIO4 as an oxidant is crucial for the catalytic reaction. These new, inexpensive reaction conditions allow the gram-scale synthesis of α-heteroaryl carboxylic acids.

Graphical abstract: Manganese-catalyzed intermolecular C–H/C–H coupling of carbonyls and heteroarenes

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Publication details

The article was received on 24 Jan 2014, accepted on 04 Mar 2014 and first published on 04 Mar 2014


Article type: Communication
DOI: 10.1039/C4CC01376J
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Chem. Commun., 2014,50, 4105-4107

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    Manganese-catalyzed intermolecular C–H/C–H coupling of carbonyls and heteroarenes

    K. Hattori, A. Ziadi, K. Itami and J. Yamaguchi, Chem. Commun., 2014, 50, 4105
    DOI: 10.1039/C4CC01376J

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