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Issue 18, 2014
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Direct access to isoindolines through tandem Rh(iii)-catalyzed alkenylation and cyclization of N-benzyltriflamides

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Abstract

The rhodium-catalyzed oxidative alkenylation of N-benzyltriflamides with olefins followed by an intramolecular cyclization via C–H bond activation is described. This method results in the direct and efficient synthesis of highly substituted isoindoline frameworks.

Graphical abstract: Direct access to isoindolines through tandem Rh(iii)-catalyzed alkenylation and cyclization of N-benzyltriflamides

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Supplementary files

Article information


Submitted
14 Dec 2013
Accepted
06 Jan 2014
First published
07 Jan 2014

Chem. Commun., 2014,50, 2350-2352
Article type
Communication
Author version available

Direct access to isoindolines through tandem Rh(III)-catalyzed alkenylation and cyclization of N-benzyltriflamides

N. K. Mishra, J. Park, S. Sharma, S. Han, M. Kim, Y. Shin, J. Jang, J. H. Kwak, Y. H. Jung and I. S. Kim, Chem. Commun., 2014, 50, 2350 DOI: 10.1039/C3CC49486A

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