Issue 18, 2014
From the journal:

Chemical Communications

[Ag70(PW9O34)2(tBuC[triple bond, length as m-dash]C)44(H2O)2]8+: ionothermal synthesis of a silver cluster encapsulating lacunary polyoxometalate ions†

Zhan-Guo Jiang,a   Kang Shi,a   Yu-Mei Lin*a  and  Quan-Ming Wang*a  

* Corresponding authors

a State Key Lab of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering Xiamen, P. R. China
E-mail: linyum@xmu.edu.cn, qmwang@xmu.edu.cn
Fax: +86-592-2183047
Tel: +86-592-2184185

Abstract

A silver alkynyl cluster containing a Ag70 shell and two lacunary [PW9O34]9− templating ions was synthesized by an ionothermal approach. Fast core–shell electronic communication between silver(I) centers and polyoxometalates was verified via cyclic voltammetry studies in [BMIm]BF4.

Graphical abstract: [Ag70(PW9O34)2(tBuC [[triple bond, length as m-dash]] C)44(H2O)2]8+: ionothermal synthesis of a silver cluster encapsulating lacunary polyoxometalate ions

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Article information

DOI
https://doi.org/10.1039/C3CC49290G
Article type
Communication
Submitted
06 Dec 2013
Accepted
06 Jan 2014
First published
08 Jan 2014

Chem. Commun., 2014,50, 2353-2355

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[Ag70(PW9O34)2(tBuC[triple bond, length as m-dash]C)44(H2O)2]8+: ionothermal synthesis of a silver cluster encapsulating lacunary polyoxometalate ions

Z. Jiang, K. Shi, Y. Lin and Q. Wang, Chem. Commun., 2014, 50, 2353 DOI: 10.1039/C3CC49290G

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