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Issue 17, 2014
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Highly regioselective and chemoselective titanocene mediated Barbier-type allylation reactions

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Abstract

Titanocene carboxylate 1 is an excellent chemoselective reagent for unprecedented α-regioselective Barbier-type reactions. It constitutes the first titanocene(III) able to tolerate epoxides and readily reduced carbonyl compounds, such as aromatic and α,β-unsaturated aldehydes.

Graphical abstract: Highly regioselective and chemoselective titanocene mediated Barbier-type allylation reactions

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Supplementary files

Article information


Submitted
04 Dec 2013
Accepted
24 Dec 2013
First published
06 Jan 2014

This article is Open Access

Chem. Commun., 2014,50, 2211-2213
Article type
Communication
Author version available

Highly regioselective and chemoselective titanocene mediated Barbier-type allylation reactions

S. P. Morcillo, Á. Martínez-Peragón, V. Jakoby, A. J. Mota, C. Kube, J. Justicia, J. M. Cuerva and A. Gansäuer, Chem. Commun., 2014, 50, 2211
DOI: 10.1039/C3CC49230C

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