Issue 17, 2014

Double Smiles rearrangement of Passerini adducts towards benzoxazinones

Abstract

A new straightforward access to benzoxazinones based on a three-component coupling is presented here. The mechanism of the whole process involves a double aryl transfer as clearly underlined by the X-ray diffraction analysis of the products.

Graphical abstract: Double Smiles rearrangement of Passerini adducts towards benzoxazinones

Supplementary files

Article information

Article type
Communication
Submitted
26 Nov 2013
Accepted
20 Dec 2013
First published
23 Dec 2013

Chem. Commun., 2014,50, 2214-2217

Author version available

Double Smiles rearrangement of Passerini adducts towards benzoxazinones

E. Martinand-Lurin, A. Dos Santos, L. El Kaim, L. Grimaud and P. Retailleau, Chem. Commun., 2014, 50, 2214 DOI: 10.1039/C3CC49022J

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