Issue 36, 2013

A fine tuning of metallaborane to bridged-boryl complex, [(Cp*Ru)2(μ-H)(μ-CO)(μ-Bcat)] (cat = 1,2-O2C6H4; Cp* = η5-C5Me5)

Abstract

Room temperature photolysis of [(Cp*RuCO)2BH4(Bcat)], 3, generated from the reaction of arachno-[(Cp*RuCO)2B2H6], 1, with HBcat (cat = 1,2-O2C6H4), yielded a rare homodinuclear bridged-boryl complex, [(Cp*Ru)2(μ-H)(μ-CO)(μ-Bcat)], 4, confirmed by X-ray diffraction.

Graphical abstract: A fine tuning of metallaborane to bridged-boryl complex, [(Cp*Ru)2(μ-H)(μ-CO)(μ-Bcat)] (cat = 1,2-O2C6H4; Cp* = η5-C5Me5)

Supplementary files

Article information

Article type
Communication
Submitted
01 May 2013
Accepted
03 Jul 2013
First published
03 Jul 2013

Dalton Trans., 2013,42, 12828-12831

A fine tuning of metallaborane to bridged-boryl complex, [(Cp*Ru)2(μ-H)(μ-CO)(μ-Bcat)] (cat = 1,2-O2C6H4; Cp* = η5-C5Me5)

R. S. Anju, D. K. Roy, K. Geetharani, B. Mondal, B. Varghese and S. Ghosh, Dalton Trans., 2013, 42, 12828 DOI: 10.1039/C3DT51138C

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