Issue 36, 2013
From the journal:

Dalton Transactions

A cationic and ferromagnetic hexametallic Mn(iii) single-molecule magnet based on the salicylamidoxime ligand†‡

José Martínez-Lillo,*a   Neil Dolana  and  Euan K. Brechin*a  

* Corresponding authors

a EaStCHEM School of Chemistry, The University of Edinburgh, West Mains Road, Edinburgh, Scotland, UK
E-mail: fmartine@staffmail.ed.ac.uk, ebrechin@staffmail.ed.ac.uk
Fax: +44 (0)131 650 6453
Tel: +44 (0)131 650 7545

Abstract

The salicylamidoxime-based complex [Mn6(μ3-O)2(H2N-sao)6(py)6(EtOH)2](ClO4)2·4EtOH (1·4EtOH) constitutes the first example of a cationic and ferromagnetic member of the oxime-based family of [MnIII6] single-molecule magnets.

Graphical abstract: A cationic and ferromagnetic hexametallic Mn(iii) single-molecule magnet based on the salicylamidoxime ligand

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Article information

DOI
https://doi.org/10.1039/C3DT51512E
Article type
Communication
Submitted
07 Jun 2013
Accepted
09 Jul 2013
First published
11 Jul 2013

Dalton Trans., 2013,42, 12824-12827

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A cationic and ferromagnetic hexametallic Mn(III) single-molecule magnet based on the salicylamidoxime ligand

J. Martínez-Lillo, N. Dolan and E. K. Brechin, Dalton Trans., 2013, 42, 12824 DOI: 10.1039/C3DT51512E

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