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Issue 1, 2013
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A porous Sm(III) coordination nanotube with hydrophobic and hydrophilic channels

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Abstract

The π–π stacking interactions between tptz units from adjacent Sm(tptz)(HCOO)3 coordination nanotubes leads to additional 1D channels (tptz = 2,4,6-tris(2-pyridyl)-s-triazine). The present compound is a rare case of a tubular porous material with both hydrophobic and hydrophilic channels. Permanent porosity was confirmed by N2 adsorption isotherms.

Graphical abstract: A porous Sm(iii) coordination nanotube with hydrophobic and hydrophilic channels

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Publication details

The article was received on 12 Aug 2012, accepted on 12 Oct 2012 and first published on 02 Nov 2012


Article type: Communication
DOI: 10.1039/C2DT31842C
Dalton Trans., 2013,42, 54-57

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    A porous Sm(III) coordination nanotube with hydrophobic and hydrophilic channels

    N. Lopez, H. Zhao, D. Zhao, H. Zhou, J. P. Riebenspies and K. R. Dunbar, Dalton Trans., 2013, 42, 54
    DOI: 10.1039/C2DT31842C

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