Single-molecule magnet based on a C-type polyoxomolybdate with an S = 11 ground state: [Fe5CoMo22As2O85(H2O)]15−

Yanzhong Zhen; Bin Liu; Lili Li; Danjun Wang; Ying Ma; Huaiming Hu; Shengli Gao; Ganglin Xue

doi:10.1039/C2DT31331F

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Single-molecule magnet based on a C-type polyoxomolybdate with an S = 11 ground state: [Fe₅CoMo₂₂As₂O₈₅(H₂O)]¹⁵⁻†

Yanzhong Zhen,^ab Bin Liu,^a Lili Li,^a Danjun Wang,^ab Ying Ma,^a Huaiming Hu,^a Shengli Gao^a and Ganglin Xue*^a

Author affiliations

* Corresponding authors

^a Key Laboratory of Synthetic and Natural Functional Molecule Chemistry (Ministry of Education), Department of Chemistry, Northwest University, Xi'an, 710069, China
E-mail: xglin707@163.com

^b College of Chemistry & Chemical Engineering, Yan'an University, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan'an 716000, China

Abstract

A C-type polyoxomolybdate containing a mixed-transition metal cluster Fe₅Co has been prepared as an ammonium salt, (NH₄)₁₅[Fe₅CoMo₂₂As₂O₈₅(H₂O)]·15H₂O (1). Interestingly, the magnetism measurements show that the compound exhibits not only an overall ferromagnetic cluster with a large spin ground state of S = 11 but also the behavior of single-molecule magnets.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C2DT31331F
Article type: Communication
Submitted: 21 Jun 2012
Accepted: 19 Oct 2012
First published: 22 Oct 2012

Download Citation

Dalton Trans., 2013,42, 58-62

Permissions

Request permissions

Single-molecule magnet based on a C-type polyoxomolybdate with an S = 11 ground state: [Fe₅CoMo₂₂As₂O₈₅(H₂O)]¹⁵⁻

Y. Zhen, B. Liu, L. Li, D. Wang, Y. Ma, H. Hu, S. Gao and G. Xue, Dalton Trans., 2013, 42, 58 DOI: 10.1039/C2DT31331F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Dalton Transactions