Issue 2, 2013
From the journal:

Dalton Transactions

A highly stable polypyridyl-based cobalt catalyst for homo- and heterogeneous photocatalytic water reduction†

Miguel Guttentag,a   Alexander Rodenberg,b   Cyril Bachmann,a   Anna Senn,a   Peter Hamm*b  and  Roger Alberto*a  

* Corresponding authors

a Institute of Inorganic Chemistry, University of Zürich, Winterthurerstr. 190, 8057 Zürich, Switzerland
E-mail: ariel@aci.uzh.ch
Fax: +41 44 63 568 02
Tel: +41 44 63 546 80

b Institute of Physical Chemistry, University of Zürich, Winterthurerstr. 190, 8057 Zürich, Switzerland
E-mail: phamm@pci.uzh.ch
Fax: +41 44 63 568 13
Tel: +41 44 63 54 450 80

Abstract

Synthesis, characterization and activity in homogeneous photocatalytic hydrogen production of a cobalt polypyridyl complex are reported. TONs up to 9000 H2/Co could be achieved. Immobilization of the complex on a swellable resin yielded a recyclable heterogeneous catalyst.

Graphical abstract: A highly stable polypyridyl-based cobalt catalyst for homo- and heterogeneous photocatalytic water reduction

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Article information

DOI
https://doi.org/10.1039/C2DT31699D
Article type
Communication
Submitted
27 Jul 2012
Accepted
05 Oct 2012
First published
09 Oct 2012

Dalton Trans., 2013,42, 334-337

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A highly stable polypyridyl-based cobalt catalyst for homo- and heterogeneous photocatalytic water reduction

M. Guttentag, A. Rodenberg, C. Bachmann, A. Senn, P. Hamm and R. Alberto, Dalton Trans., 2013, 42, 334 DOI: 10.1039/C2DT31699D

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