Issue 2, 2013
From the journal:

Dalton Transactions

A further step towards tuning the properties of metal-chalcogenide nanocapsules by replacing skeletal oxide by sulphide ligands†‡

Christian Schäffer,a   Ana Maria Todea,a   Hartmut Bögge,a   Sébastien Floquet,b   Emmanuel Cadot,b   Vladimir S. Korenev,c   Vladimir P. Fedin,c   Pierre Gouzerhd  and  Achim Müller*a  

* Corresponding authors

a Fakultät für Chemie, Universität Bielefeld, Postfach 100131, 33501 Bielefeld, Germany
E-mail: a.mueller@uni-bielefeld.de
Web: http://www.uni-bielefeld.de/chemie/ac1/
Fax: +49 521-106-6003

b Institut Lavoisier de Versailles, UMR CNRS 8180, Université de Versailles St-Quentin, 45 avenue des Etats Unis, 78035 Versailles, France

c Nikolaev Institute of Inorganic Chemistry SB RAS, Prospect Lavrentyeva 3, 630090 Novosibirsk, Russia

d Institut Parisien de Chimie Moléculaire, UMR CNRS 7201, UPMC Univ Paris 06, Sorbonne Universités, Case courrier 42, 4 Place Jussieu, 75252 Paris, France

Abstract

Addition of [Mo2VO2(μ-O)(μ-S)(aq)]2+ linker-type units to a solution/dynamic library containing tungstates results via the formation of the complementary pentagonal {(W)W5} units logically in the self-assembly of a mixed oxide/sulphide {WVI72MoV60}-type Keplerate, thereby demonstrating the ability to tune the capsule's skeletal softness (the (μ-O)2 and (μ-S)2 scenarios are known) and providing options to influence differently important capsule–substrate interactions.

Graphical abstract: A further step towards tuning the properties of metal-chalcogenide nanocapsules by replacing skeletal oxide by sulphide ligands

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Article information

DOI
https://doi.org/10.1039/C2DT32247A
Article type
Communication
Submitted
25 Sep 2012
Accepted
29 Oct 2012
First published
29 Oct 2012

Dalton Trans., 2013,42, 330-333

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A further step towards tuning the properties of metal-chalcogenide nanocapsules by replacing skeletal oxide by sulphide ligands

C. Schäffer, A. M. Todea, H. Bögge, S. Floquet, E. Cadot, V. S. Korenev, V. P. Fedin, P. Gouzerh and A. Müller, Dalton Trans., 2013, 42, 330 DOI: 10.1039/C2DT32247A

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