Issue 11, 2013
From the journal:

Catalysis Science & Technology

Substrate selectivity in the alkyne hydration mediated by NHC–Au(i) controlled by encapsulation of the catalyst within a hydrogen bonded hexameric host†

Alessandra Cavarzan,a   Joost N. H. Reek,b   Francesco Trentin,a   Alessandro Scarso*a  and  Giorgio Strukul*a  

* Corresponding authors

a Dipartimento di Scienze Molecolari e Nanosistemi, Universitá Ca' Foscari di Venezia, Calle Larga S. Marta 2137, Venezia, Italy
E-mail: alesca@unive.it, strukul@unive.it
Fax: +39-041-2340517
Tel: +39-041-2348569

b Van't Hoff Institute for Molecular Sciences, University of Amsterdam, Postbus 94720, 1090 GE Amsterdam, The Netherlands

Abstract

Significant alterations in the substrate selectivity in the alkyne hydration reaction catalyzed by NHC–Au(I) 1 are observed as a consequence of encapsulation of the homogeneous catalyst within a hexameric resorcin[4]arene based hydrogen bonded self-assembled host.

Graphical abstract: Substrate selectivity in the alkyne hydration mediated by NHC–Au(i) controlled by encapsulation of the catalyst within a hydrogen bonded hexameric host

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Article information

DOI
https://doi.org/10.1039/C3CY00300K
Article type
Communication
Submitted
30 Apr 2013
Accepted
21 Jul 2013
First published
22 Jul 2013

Catal. Sci. Technol., 2013,3, 2898-2901

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Substrate selectivity in the alkyne hydration mediated by NHC–Au(I) controlled by encapsulation of the catalyst within a hydrogen bonded hexameric host

A. Cavarzan, J. N. H. Reek, F. Trentin, A. Scarso and G. Strukul, Catal. Sci. Technol., 2013, 3, 2898 DOI: 10.1039/C3CY00300K

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