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Issue 11, 2013
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A silver-free system for the direct C–H auration of arenes and heteroarenes from gold chloride complexes

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Abstract

A new methodology for the direct C–H auration of electron-deficient arenes and heteroarenes with simple bases and readily available [Au(PR3)Cl] complexes is described. This system allows the preparation of a wide scope of aryl–Au(I) compounds without the need for using Ag(I) additives or preparing and isolating basic Au(I) hydroxide complexes.

Graphical abstract: A silver-free system for the direct C–H auration of arenes and heteroarenes from gold chloride complexes

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Publication details

The article was received on 12 Apr 2013, accepted on 13 Jun 2013 and first published on 14 Jun 2013


Article type: Communication
DOI: 10.1039/C3CY00240C
Citation: Catal. Sci. Technol., 2013,3, 2892-2897
  • Open access: Creative Commons BY license
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    A silver-free system for the direct C–H auration of arenes and heteroarenes from gold chloride complexes

    N. Ahlsten, G. J. P. Perry, X. C. Cambeiro, T. C. Boorman and I. Larrosa, Catal. Sci. Technol., 2013, 3, 2892
    DOI: 10.1039/C3CY00240C

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