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Issue 82, 2013
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Identification of bridged CO2 binding in a Prussian blue analogue using neutron powder diffraction

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Abstract

Neutron powder diffraction measurements were carried out on the evacuated and CO2-loaded Prussian blue analogue, Fe3[Co(CN)6]2, identifying two distinct CO2 adsorption sites: site A, in which CO2 uniquely bridges between two bare-metal sites, and site B, in which it interacts in a face capping motif. The saturation of site A at low loadings of CO2 demonstrates the favourable nature of the interaction of CO2 with bare-metal sites within the material.

Graphical abstract: Identification of bridged CO2 binding in a Prussian blue analogue using neutron powder diffraction

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Article information


Submitted
07 Aug 2013
Accepted
30 Aug 2013
First published
02 Sep 2013

Chem. Commun., 2013,49, 9404-9406
Article type
Communication

Identification of bridged CO2 binding in a Prussian blue analogue using neutron powder diffraction

S. H. Ogilvie, S. G. Duyker, P. D. Southon, V. K. Peterson and C. J. Kepert, Chem. Commun., 2013, 49, 9404
DOI: 10.1039/C3CC46019C

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