Issue 81, 2013
From the journal:

Chemical Communications

[Pb(Tab)2(4,4′-bipy)](PF6)2: two-step ambient temperature quantitative solid-state synthesis, structure and dielectric properties†

Fan Wang,a   Chun-Yan Ni,a   Quan Liu,a   Fu-Ling Li,a   Jing Shi,a   Hong-Xi Lia  and  Jian-Ping Lang*ab  

* Corresponding authors

a College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, Jiangsu, P. R. China
E-mail: jplang@suda.edu.cn
Fax: +86-512-65880089

b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, P. R. China

Abstract

Ambient temperature solid-state reaction of Pb(OAc)2 with TabHPF6 afforded an intermediate product [Pb(Tab)2]2(PF6)4, which further reacted with 4,4′-bipy in the solid state to generate a unique 2D cationic coordination polymer [Pb(Tab)2(4,4′-bipy)](PF6)2 in quantitative yield. Both complexes possess a low dielectric constant and low dielectric loss in the high electric field frequency range.

Graphical abstract: [Pb(Tab)2(4,4′-bipy)](PF6)2: two-step ambient temperature quantitative solid-state synthesis, structure and dielectric properties

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Supplementary files

Article information

DOI
https://doi.org/10.1039/C3CC45066J
Article type
Communication
Submitted
05 Jul 2013
Accepted
27 Jul 2013
First published
30 Jul 2013

Chem. Commun., 2013,49, 9248-9250

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[Pb(Tab)2(4,4′-bipy)](PF6)2: two-step ambient temperature quantitative solid-state synthesis, structure and dielectric properties

F. Wang, C. Ni, Q. Liu, F. Li, J. Shi, H. Li and J. Lang, Chem. Commun., 2013, 49, 9248 DOI: 10.1039/C3CC45066J

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