Synthesis of pentadecaphenylenes, their inclusion properties, and nanostructure formation with C60

M. Jalilur Rahman; Hideyuki Shimizu; Yasuyuki Araki; Hiroshi Ikeda; Masahiko Iyoda

doi:10.1039/C3CC42922A

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Synthesis of pentadecaphenylenes, their inclusion properties, and nanostructure formation with C₆₀†

M. Jalilur Rahman,‡^a Hideyuki Shimizu,‡^a Yasuyuki Araki,^b Hiroshi Ikeda^c and Masahiko Iyoda*^a

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* Corresponding authors

^a Department of Chemistry, Graduate School of Science and Engineering, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan
E-mail: iyoda@tmu.ac.jp
Fax: +81-42-677-2525
Tel: +81-42-677-2731

^b Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-2 Katahira, Aoba-ku, Sendai 980-8577, Japan

^c Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8531, Japan

Abstract

Synthesis of macrocyclic pentadecaphenylene was carried out via electron-transfer oxidation of the corresponding Lipshutz cuprate. Pentadecaphenylene self-aggregated in solution to form a gel. Furthermore, it incorporated C₆₀ in its cavity to produce a fibrous inclusion complex which showed a high gelation ability in benzene.

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Article information

DOI: https://doi.org/10.1039/C3CC42922A
Article type: Communication
Submitted: 19 Apr 2013
Accepted: 25 May 2013
First published: 28 May 2013

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Chem. Commun., 2013,49, 9251-9253

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Synthesis of pentadecaphenylenes, their inclusion properties, and nanostructure formation with C₆₀

M. J. Rahman, H. Shimizu, Y. Araki, H. Ikeda and M. Iyoda, Chem. Commun., 2013, 49, 9251 DOI: 10.1039/C3CC42922A

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Chemical Communications