Issue 74, 2013
From the journal:

Chemical Communications

Vanadium-catalyzed deoxydehydration of glycols†

Garry Chapman, Jr.a  and  Kenneth M. Nicholas*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, University of Oklahoma, Norman, Oklahoma 73019, USA
E-mail: knicholas@ou.edu
Fax: +1-405-325-6111
Tel: +1-405-325-3696

Abstract

A survey of several metavandate (VO3−) and chelated dioxovanadium derivatives shows that tetrabutylammonium dioxovanadium(V)dipicolinate most effectively catalyzes the deoxydehydration (DODH) of glycols to olefins in moderate to excellent yields with triphenylphosphine or sodium sulfite as reductants.

Graphical abstract: Vanadium-catalyzed deoxydehydration of glycols

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Article information

DOI
https://doi.org/10.1039/C3CC44656E
Article type
Communication
Submitted
22 Jun 2013
Accepted
23 Jul 2013
First published
25 Jul 2013

Chem. Commun., 2013,49, 8199-8201

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Vanadium-catalyzed deoxydehydration of glycols

G. Chapman and K. M. Nicholas, Chem. Commun., 2013, 49, 8199 DOI: 10.1039/C3CC44656E

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