Issue 54, 2013
From the journal:

Chemical Communications

Near-IR luminescent neodymium complexes: spectroscopic probes for hydroamination catalysis†

Stacey D. Bennett,a   Simon J. A. Popea  and  Benjamin D. Ward*a  

* Corresponding authors

a School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff CF10 3AT, UK
E-mail: WardBD@Cardiff.ac.uk
Fax: +44 (0)29 208 74030
Tel: +44 (0)29 208 70302

Abstract

Neodymium complexes bearing the sensitising bis(oxazolinylphenyl)amine (BOPA) ligands have been prepared, and analysed spectroscopically under both catalytic and pseudo-catalytic conditions with respect to the intramolecular hydroamination of an aminoalkene, providing a direct means of monitoring binding events and relative space around the metal centre.

Graphical abstract: Near-IR luminescent neodymium complexes: spectroscopic probes for hydroamination catalysis

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Article information

DOI
https://doi.org/10.1039/C3CC42923G
Article type
Communication
Submitted
19 Apr 2013
Accepted
24 May 2013
First published
28 May 2013
This article is Open Access
Creative Commons BY license

Chem. Commun., 2013,49, 6072-6074

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Near-IR luminescent neodymium complexes: spectroscopic probes for hydroamination catalysis

S. D. Bennett, S. J. A. Pope and B. D. Ward, Chem. Commun., 2013, 49, 6072 DOI: 10.1039/C3CC42923G

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