Issue 54, 2013
From the journal:

Chemical Communications

Intramolecular reorganization energy in zinc phthalocyanine and its fluorinated derivatives: a joint experimental and theoretical study†

Demetrio A. da Silva Filho,*ab   Veaceslav Coropceanu,b   Nadine E. Gruhn,‡c   Pedro Henrique de Oliveira Netoa  and  Jean-Luc Brédas*b  

* Corresponding authors

a Institute of Physics, University of Brasília, C.P. 04455, DF, Brazil
E-mail: dasf@unb.br
Fax: +55 61-3307-2363
Tel: +55 61-3107-6089

b School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, Georgia 30332-0400, USA
E-mail: jean-luc.bredas@chemistry.gatech.edu

c Department of Chemistry, University of Arizona, Tucson, Arizona, USA

Abstract

We report a high-resolution gas-phase UPS spectrum of zinc phthalocyanine (ZnPc) together with a detailed analysis of the vibronic structure of the first ionization band, showing that ZnPc presents the lowest value of the intramolecular reorganization energy experimentally reported for a molecular organic semiconductor.

Graphical abstract: Intramolecular reorganization energy in zinc phthalocyanine and its fluorinated derivatives: a joint experimental and theoretical study

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Article information

DOI
https://doi.org/10.1039/C3CC42003E
Article type
Communication
Submitted
18 Mar 2013
Accepted
21 May 2013
First published
22 May 2013

Chem. Commun., 2013,49, 6069-6071

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Intramolecular reorganization energy in zinc phthalocyanine and its fluorinated derivatives: a joint experimental and theoretical study

D. A. da Silva Filho, V. Coropceanu, N. E. Gruhn, P. H. de Oliveira Neto and J. Brédas, Chem. Commun., 2013, 49, 6069 DOI: 10.1039/C3CC42003E

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