One-step synthesis of Ni3S2 nanorod@Ni(OH)2nanosheet core–shell nanostructures on a three-dimensional graphene network for high-performance supercapacitors

Abstract

A three-dimensional graphene network (3DGN) grown on nickel foam is an excellent template for the synthesis of graphene-based composite electrodes for use in supercapacitors. Ni(OH)₂nanosheets coated onto single-crystal Ni₃S₂nanorods grown on the surface of the 3DGN (referred to as the Ni₃S₂@Ni(OH)₂/3DGN) are synthesized using a one-step hydrothermal reaction. SEM, TEM, XRD and Raman spectroscopy are used to investigate the morphological and structural evolution of the Ni₃S₂@Ni(OH)₂/3DGN. Detailed electrochemical characterization shows that the Ni₃S₂@Ni(OH)₂/3DGN exhibits high specific capacitance (1277 F g⁻¹ at 2 mV s⁻¹ and 1037.5 F g⁻¹ at 5.1 A g⁻¹) and areal capacitance (4.7 F cm⁻² at 2 mV s⁻¹ and 3.85 F cm⁻² at 19.1 mA cm⁻²) with good cycling performance (99.1% capacitance retention after 2000 cycles).