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Issue 27, 2013
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Rewriting the bacterial glycocalyx via Suzuki–Miyaura cross-coupling

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Abstract

Suzuki–Miyaura cross-coupling has been used to couple novel carbohydrate-based boronic acids, site-selectively, to the surface of E. coli at an unnatural amino acid. In this way, benign metal-catalyzed cellular switching allowed modulation of interactions with biomolecular partners via prokaryotic O-glycosylation mimics.

Graphical abstract: Rewriting the bacterial glycocalyx via Suzuki–Miyaura cross-coupling

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Article information


Submitted
09 Dec 2012
Accepted
08 Jan 2013
First published
08 Jan 2013

Chem. Commun., 2013,49, 2747-2749
Article type
Communication

Rewriting the bacterial glycocalyx via Suzuki–Miyaura cross-coupling

C. D. Spicer and B. G. Davis, Chem. Commun., 2013, 49, 2747
DOI: 10.1039/C3CC38824G

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