Issue 27, 2013

A sodium manganese ferrocyanide thin film for Na-ion batteries

Abstract

A thin film of sodium manganese ferrocyanide, Na1.32Mn[Fe(CN)6]0.83·3.5H2O, exhibits discharge capacity (= 109 mA h g−1) and discharge voltage (3.4 V in average) at 0.5 C against Na in aprotic solvent. The ex situ XRD experiments reveal that the host framework remains cubic without showing any structural phase transition during the charge process. The discharge property is discernible up to 40 C.

Graphical abstract: A sodium manganese ferrocyanide thin film for Na-ion batteries

Article information

Article type
Communication
Submitted
10 Dec 2012
Accepted
03 Feb 2013
First published
04 Feb 2013

Chem. Commun., 2013,49, 2750-2752

A sodium manganese ferrocyanide thin film for Na-ion batteries

T. Matsuda, M. Takachi and Y. Moritomo, Chem. Commun., 2013, 49, 2750 DOI: 10.1039/C3CC38839E

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