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Issue 30, 2013
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Lanthanide corroles: a new class of macrocyclic lanthanide complexes

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Abstract

The first examples of lanthanide corroles are prepared by two synthetic routes. (Mes2(p-OMePh)corrole)La·4.5DME (1·4.5DME) and (Mes2(p-OMePh)corrole)Tb·4DME (2·4DME) are prepared from the free base corrole and Ln((NSiMe3)2)3, while (Mes2(p-OMePh)corrole)Gd·TACNMe3 (3·TACNMe3) is prepared by metathesis of the recently reported Li3 corrole and GdCl3.

Graphical abstract: Lanthanide corroles: a new class of macrocyclic lanthanide complexes

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Article information


Submitted
08 Dec 2012
Accepted
26 Feb 2013
First published
28 Feb 2013

Chem. Commun., 2013,49, 3104-3106
Article type
Communication

Lanthanide corroles: a new class of macrocyclic lanthanide complexes

H. L. Buckley, M. R. Anstey, D. T. Gryko and J. Arnold, Chem. Commun., 2013, 49, 3104
DOI: 10.1039/C3CC38806A

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