A novel strategy of initiating an organocatalysed dynamic kinetic resolution (dr up to 99 : 1 and er up to 94 : 6) for the synthesis of chiral trans-2,5-dialkylcyclohexanones by an asymmetric conjugate addition of dimethyl malonate on to 6-substituted cyclohexenones is reported.
G. Pandey, P. A. Adate and V. G. Puranik, Org. Biomol. Chem., 2012, 10, 8260 DOI: 10.1039/C2OB26597D
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