Issue 33, 2012
From the journal:

Organic & Biomolecular Chemistry

Asymmetric organocatalytic diboration of alkenes†‡

Amadeu Bonet,a   Cristina Sole,a   Henrik Gulyás*a  and  Elena Fernández*a  

* Corresponding authors

a Dept. Química Física i Inorgànica, University Rovira i Virgili, C/Marcel·lí Domingo s/n, 43007 Tarragona, Spain
E-mail: mariaelena.fernandez@urv.cat
Web: http://argo.urv.es/tecat/catalytic_organoborane_chemistry.php

Abstract

The use of chiral alcohols to form the Lewis acid–base *RO− → bis(pinacolato)diboron adduct, in situ, provides an opportunity to induce asymmetry in the organocatalytic diboration of alkenes and complements the well established transition metal-mediated enantioselective diboration.

Graphical abstract: Asymmetric organocatalytic diboration of alkenes

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Article information

DOI
https://doi.org/10.1039/C2OB26079D
Article type
Communication
Submitted
04 Jun 2012
Accepted
05 Jul 2012
First published
06 Jul 2012

Org. Biomol. Chem., 2012,10, 6621-6623

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Asymmetric organocatalytic diboration of alkenes

A. Bonet, C. Sole, H. Gulyás and E. Fernández, Org. Biomol. Chem., 2012, 10, 6621 DOI: 10.1039/C2OB26079D

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