Issue 33, 2012

Essential reactive intermediates in nucleoside chemistry: cyclonucleoside cations

Abstract

DFT-based modeling as well as experimental examination of model keto nucleosides have revealed that high susceptibility of these compounds to acids is due to formation of intermediate cyclonucleoside cations of low energy. Theoretically established chemical structures of these previously overlooked intermediates explain the reaction courses for a cluster of nucleoside reactions.

Graphical abstract: Essential reactive intermediates in nucleoside chemistry: cyclonucleoside cations

Supplementary files

Article information

Article type
Communication
Submitted
06 May 2012
Accepted
03 Jul 2012
First published
05 Jul 2012

Org. Biomol. Chem., 2012,10, 6624-6628

Essential reactive intermediates in nucleoside chemistry: cyclonucleoside cations

A. M. Belostotskii, E. Genizi and A. Hassner, Org. Biomol. Chem., 2012, 10, 6624 DOI: 10.1039/C2OB25868D

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