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Issue 26, 2012
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Generation of [(IPr)Pd(PR2Cl)] complexes via P–Cl reductive elimination

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Abstract

Treatment of [(IPr)Pd(Cl)2(PR2H)] (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene; R = Cy, tBu, or 1-Ad) with NaN(SiMe3)2 generated isolable [(IPr)Pd(PR2Cl)] complexes (68–75%) that have been crystallographically characterized. The formation of these mixed-ligand Pd(0) species in this manner corresponds to an unusual net dehydrohalogenation/P–Cl reductive elimination sequence.

Graphical abstract: Generation of [(IPr)Pd(PR2Cl)] complexes via P–Cl reductive elimination

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Supplementary files

Article information


Submitted
11 Oct 2011
Accepted
10 Nov 2011
First published
16 Dec 2011

Dalton Trans., 2012,41, 7883-7885
Article type
Communication

Generation of [(IPr)Pd(PR2Cl)] complexes via P–Cl reductive elimination

B. J. Tardiff, K. D. Hesp, M. J. Ferguson and M. Stradiotto, Dalton Trans., 2012, 41, 7883
DOI: 10.1039/C1DT11910A

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