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Issue 26, 2012
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A tris(2-quinolylmethyl)amine scaffold that promotes hydrogen bonding within the secondary coordination sphere

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Abstract

A new quinolyl-based ligand presents three amide functionalities to act as hydrogen-bond accepting groups to a metal-bound substrate at a well-defined distance. As a confirmation of the design strategy, CH3CN coordinated to copper(II) participates in CH–O interactions in the solid state and in solution.

Graphical abstract: A tris(2-quinolylmethyl)amine scaffold that promotes hydrogen bonding within the secondary coordination sphere

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Supplementary files

Article information


Submitted
20 Feb 2012
Accepted
04 May 2012
First published
10 May 2012

Dalton Trans., 2012,41, 7886-7889
Article type
Communication

A tris(2-quinolylmethyl)amine scaffold that promotes hydrogen bonding within the secondary coordination sphere

C. M. Moore and N. K. Szymczak, Dalton Trans., 2012, 41, 7886
DOI: 10.1039/C2DT30406F

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