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Issue 3, 2012
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Influence of the alkaline earth cations on the topology of MII/CuII mixed-metal–organic frameworks (M = Ca, Sr and Ba)

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Abstract

The use of the mononuclear copper(II) complex, [CuII(Me2pma)2]2 (Me2pma = N-2,6-dimethylphenyloxamate), as a bis(bidentate) metalloligand toward solvated alkaline earth metal cations affords a new series of oxamato-bridged heterobimetallic two-dimensional compounds with mixed square–octagonal [CaII2CuII3] or square [MII2CuII3] (M = Sr and Ba) layered structures of (4·82) and (44·62) net topologies, respectively.

Graphical abstract: Influence of the alkaline earth cations on the topology of MII/CuII mixed-metal–organic frameworks (M = Ca, Sr and Ba)

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Publication details

The article was received on 14 Sep 2011, accepted on 15 Nov 2011 and first published on 12 Dec 2011


Article type: Communication
DOI: 10.1039/C1CE06203D
Citation: CrystEngComm, 2012,14, 761-764

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    Influence of the alkaline earth cations on the topology of MII/CuII mixed-metal–organic frameworks (M = Ca, Sr and Ba)

    J. Ferrando-Soria, M. T. M. Rood, M. Julve, F. Lloret, Y. Journaux, J. Pasán, C. Ruiz-Pérez, O. Fabelo and E. Pardo, CrystEngComm, 2012, 14, 761
    DOI: 10.1039/C1CE06203D

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