Issue 3, 2012
From the journal:

CrystEngComm

Dryness sensitive porous 3d–4f metal–organic framework with unusual dynamic behaviour†

Oscar Fabelo,*abc   Laura Cañadillas-Delgado,abc   Jorge Pasán,a   Pau Díaz-Gallifa,a   Ana Labradord  and  Catalina Ruiz-Pérez*a  

* Corresponding authors

a Laboratorio de Rayos X y Materiales Moleculares, Dpto. de Física Fundamental II, Facultad de Física, Universidad de La Laguna, Avenida Astrofísico Francisco Sánchez s/n, La Laguna, Tenerife, Spain
E-mail: fabelo@ill.fr, caruiz@ull.es
Fax: +34 922318320
Tel: +34 922318236

b Instituto de Ciencia de Materiales de Aragón, CSIC-Universidad de Zaragoza, Pedro Cerbuna 12, Zaragoza, Spain

c Institut Laue Langevin, B.P. 156, 6 Rue J. Horowitz, Grenoble, France

d BM16 – LLS. European Synchrotron Radiation Facility, 6 Rue Jules Horowitz - BP 220, Grenoble, CEDEX 9, France

Abstract

A new three-dimensional heteronuclear metal–organic framework has been synthesized using the 1,2,4,5-benzenetetracarboxylate ligand as a linker and Pr(III)–Cu(II) dinuclear units as nodes. The resulting structure shows an unexpected dynamic behaviour, where the volume of the crystal structure is shrunk by 11.5% in a dryness atmosphere.

Graphical abstract: Dryness sensitive porous 3d–4f metal–organic framework with unusual dynamic behaviour

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Article information

DOI
https://doi.org/10.1039/C1CE06210G
Article type
Communication
Submitted
15 Sep 2011
Accepted
17 Nov 2011
First published
07 Dec 2011

CrystEngComm, 2012,14, 765-767

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Dryness sensitive porous 3d–4f metal–organic framework with unusual dynamic behaviour

O. Fabelo, L. Cañadillas-Delgado, J. Pasán, P. Díaz-Gallifa, A. Labrador and C. Ruiz-Pérez, CrystEngComm, 2012, 14, 765 DOI: 10.1039/C1CE06210G

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