Issue 65, 2012
From the journal:

Chemical Communications

Photo- and thermally induced coloration of a crystalline MOF accompanying electron transfer and long-lived charge separation in a stable host–guest system†

Yu Zeng,a   Zhiyong Fu,*a   Hengjun Chen,a   Changchun Liu,a   Shijun Liaoa  and  Jingcao Daib  

* Corresponding authors

a Key Lab for Fuel Cell Technology of Guangdong Province, Guangdong, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, China
E-mail: zyfu@scut.edu.cn
Fax: (+86) 20 8711-2965

b Institute of Materials Physical Chemistry, Huaqiao University, Quan-zhou, Fujian, China
E-mail: jcdai@hqu.edu.cn
Fax: (+86) 595 2269-0569

Abstract

A new type of electron transfer (ET) system was built via the combination of a highly stable MOF host framework and methyl viologen guest molecule. The π-stacking arrangements adjust the distance between the D–A components, contributing to the formation of an ultra long-lived charge separated state in the photo/thermo dual stimuli-responsive complex.

Graphical abstract: Photo- and thermally induced coloration of a crystalline MOF accompanying electron transfer and long-lived charge separation in a stable host–guest system

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Article information

DOI
https://doi.org/10.1039/C2CC33823H
Article type
Communication
Submitted
28 May 2012
Accepted
26 Jun 2012
First published
26 Jun 2012

Chem. Commun., 2012,48, 8114-8116

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Photo- and thermally induced coloration of a crystalline MOF accompanying electron transfer and long-lived charge separation in a stable host–guest system

Y. Zeng, Z. Fu, H. Chen, C. Liu, S. Liao and J. Dai, Chem. Commun., 2012, 48, 8114 DOI: 10.1039/C2CC33823H

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