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Issue 61, 2012
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A spin crossover ferrous complex with ordered magnetic ferric anions

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Abstract

The first tetrahaloferrate spin crossover compound, [Fe(Metz)6](FeBr4)2 (Metz = 1-methyltetrazole), is reported. The FeBr4 ions form ferromagnetically coupled 1D stacks and exhibit an antiferromagnetic order at 2.2 K, which coexists with the gradual spin crossover centred at 165 K.

Graphical abstract: A spin crossover ferrous complex with ordered magnetic ferric anions

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Article information


Submitted
23 May 2012
Accepted
07 Jun 2012
First published
26 Jun 2012

Chem. Commun., 2012,48, 7604-7606
Article type
Communication

A spin crossover ferrous complex with ordered magnetic ferric anions

O. Roubeau, M. Evangelisti and E. Natividad, Chem. Commun., 2012, 48, 7604
DOI: 10.1039/C2CC33709F

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