Issue 61, 2012
From the journal:

Chemical Communications

A spin crossover ferrous complex with ordered magnetic ferric anions†

Olivier Roubeau,*a   Marco Evangelistia  and  Eva Natividadb  

* Corresponding authors

a Instituto de Ciencia de Materiales de Aragón (ICMA), CSIC - Universidad de Zaragoza, Departamento de Física de la Materia Condensada, Pl. San Francisco s/n, 50009 Zaragoza, Spain
E-mail: roubeau@unizar.es
Fax: +34 976 76123
Tel: +34 976 762461

b Instituto de Ciencia de Materiales de Aragón (ICMA), CSIC - Universidad de Zaragoza, Sede Campus Río Ebro, María de Luna, 3, 50018 Zaragoza, Spain

Abstract

The first tetrahaloferrate spin crossover compound, [Fe(Metz)6](FeBr4)2 (Metz = 1-methyltetrazole), is reported. The FeBr4− ions form ferromagnetically coupled 1D stacks and exhibit an antiferromagnetic order at 2.2 K, which coexists with the gradual spin crossover centred at 165 K.

Graphical abstract: A spin crossover ferrous complex with ordered magnetic ferric anions

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Article information

DOI
https://doi.org/10.1039/C2CC33709F
Article type
Communication
Submitted
23 May 2012
Accepted
07 Jun 2012
First published
26 Jun 2012

Chem. Commun., 2012,48, 7604-7606

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A spin crossover ferrous complex with ordered magnetic ferric anions

O. Roubeau, M. Evangelisti and E. Natividad, Chem. Commun., 2012, 48, 7604 DOI: 10.1039/C2CC33709F

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