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Issue 66, 2012
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Donor–acceptor stabilized silaformyl chloride

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Abstract

Formyl chloride (H(Cl)C[double bond, length as m-dash]O) is unstable at room temperature and decomposes to HCl and CO. Silicon analogue of formyl chloride, silaformyl chloride IPr·SiH(Cl)[double bond, length as m-dash]O·B(C6F5)3 (3) (IPr = 1,3-bis(2,6-diisopropyl-phenyl)imidazol-2-ylidene), was stabilized by Lewis donor–acceptor ligands. Compound 3 is not only the first stable acyclic silacarbonyl compound but also the first silacarbonyl halide reported so far.

Graphical abstract: Donor–acceptor stabilized silaformyl chloride

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Supplementary files

Article information


Submitted
23 Apr 2012
Accepted
02 Jul 2012
First published
02 Jul 2012

Chem. Commun., 2012,48, 8186-8188
Article type
Communication

Donor–acceptor stabilized silaformyl chloride

R. S. Ghadwal, R. Azhakar, H. W. Roesky, K. Pröpper, B. Dittrich, C. Goedecke and G. Frenking, Chem. Commun., 2012, 48, 8186 DOI: 10.1039/C2CC32887A

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